what is schrock's contribution to olefins? - EAS

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  1. About Richard R. Schrock | The Schrock Group

    schrockgroup.mit.edu/about-richard-r-schrock

    In the last several years he has applied alkylidene chemistry toward the controlled polymerization of cyclic olefins via ring-opening-metathesis polymerization (ROMP) and to organic chemistry in collaboration with Amir H. Hoveyda. R. R.

  2. https://en.wikipedia.org/wiki/Olefin_metathesis

    "Olefin metathesis is a child of industry and, as with many catalytic processes, it was discovered by accident." As part of ongoing work in what would later become known as Ziegler–Natta catalysis Karl Ziegler discovered the conversion of ethylene into 1-butene instead of a saturated long-chain hydrocarbon (see nickel effect).

  3. https://www.mckinseyenergyinsights.com/.../refinery-reference-desk/olefins

    Olefins are unsaturated hydrocarbons containing a double bond between two carbon atoms. Examples are butylene and propylene. Olefins in finished petroleum products. In …

  4. https://www.britannica.com/science/olefin

    One of the first processes used to produce them, developed in the early 20th century, was thermal cracking (breaking down of large molecules) of petroleum …

  5. https://www.sciencedirect.com/topics/chemical-engineering/olefin

    The mechanism of olefin cracking requires protonation of an olefin to form an alkoxide intermediate, followed by β-scission of the alkoxide to form a smaller olefin and a smaller …

  6. Mensen vragen ook naar
    What is Schrock's olefin metathesis?
    Schrock entered the olefin metathesis field in 1979 as an extension of work on tantalum alkylidenes. The initial result was disappointing as reaction of CpTa (=CH−t−Bu)Cl2 with ethylene yielded only a metallacyclopentane, not metathesis products:
    en.wikipedia.org/wiki/Olefin_metathesis
    What are olefins?
    Produced from natural gas liquids (NGLs), olefins are important building blocks for other chemicals, plastics and fibers. We gather, buy, sell and fractionate NGLs, then manufacture and market olefin products such as ethylene and propylene from our production facilities all over the world.
    www.cpchem.com/what-we-do/solutions/olefins
    Zoeken naar:What are olefins?
    What is the mechanism of cracking an olefin?
    The mechanism of olefin cracking requires protonation of an olefin to form an alkoxide intermediate, followed by β-scission of the alkoxide to form a smaller olefin and a smaller alkoxide. The smaller alkoxide subsequently desorbs to form another olefin and leaves behind a proton to regenerate the acid site.
    www.sciencedirect.com/topics/chemical-engineering/olefin
    What is the hybridisation of olefin?
    The olefins are generally known as alkenes. The olefin formula is CnH2n. The carbon at the double bond position is sp2 hybridised. The double bond present in the olefins acts as a functional group. Did You Know? Olefins can be prepared by the cracking of alkanes.
  7. https://www.cpchem.com/what-we-do/solutions/olefins

    Produced from natural gas liquids (NGLs), olefins are important building blocks for other chemicals, plastics and fibers. We gather, buy, sell and fractionate NGLs, then manufacture and market olefin products such as ethylene and …

  8. https://www.vedantu.com/chemistry/olefin

    Olefins have the ability to undergo polymerisation reactions. Olefins give Markovnikov reactions and anti-Markovnikov reactions. Olefin Chemical Formula The olefins are generally known as …

  9. Expansion of the Olefin Complex - PKN Orlen

    https://www.orlen.pl/en/about-the-company/Key-projects/olefins

    The output of the New Olefins Complex, scheduled for launch in 2025, will have versatile applications, including in the manufacture of automotive parts, components for home …

  10. Methanol to Olefins – Chemical production and investment cost

    https://www.spglobal.com/commodityinsights/en/ci/products/chemical...

    The recent dramatic increase in oil prices is reviving a strong interest in the production of light olefins from non-petroleum source among which low-cost methanol may play a significant role. …

  11. Addition of Carbon Tetrachloride and Chloroform to Olefins

    https://www.science.org/doi/10.1126/science.102.2640.128.a

    NASA reaffirms decision to keep James Webb’s name on space telescope. Competition between respiratory viruses may hold off a ‘tripledemic’ this winter. Finnish astronomers acquitted in …



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